Assymmetric induction in cyclopropanation with homogeneous and immobilised chiral metal -diketonate catalyst

Matlin, S.A., Lough, John, Chan, L., Abram, D.M.H. and Zhou, Z. (1984) Assymmetric induction in cyclopropanation with homogeneous and immobilised chiral metal -diketonate catalyst. Journal of the Chemical Society, Chemical Communications, 1038 (15). pp. 1038-1040. ISSN C39840001039

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Abstract

Copper complexes of 3-trifluoroacetyl-(+)-camphor and two of its drivatives give high optical yields when used ascatalysts for the asymmetric cyclopropanation of styrene with 2-diazodimedone; an immobilised analogue of these homogeneous catalysts retains high activity, is readily recovered, and has portential for recycling.

Item Type: Article
Subjects: Sciences
Divisions: Faculty of Applied Sciences
Faculty of Applied Sciences > Department of Pharmacy Health and Wellbeing
Depositing User: Paula Normington
Date Deposited: 12 Jun 2017 13:33
Last Modified: 12 Jun 2017 13:33
URI: http://sure.sunderland.ac.uk/id/eprint/6386

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